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Volume 66 
Part 3 
Page m309  
March 2010  

Received 10 February 2010
Accepted 12 February 2010
Online 17 February 2010

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Key indicators
Single-crystal X-ray study
T = 293 K
Mean [sigma](C-C) = 0.008 Å
R = 0.043
wR = 0.111
Data-to-parameter ratio = 19.1
Details
Open access

Dicyclohexyl{3-hydroxy-N'-[1-(2-oxidophenyl-[kappa]O)ethylidene]-2-naphthohydrazidato-[kappa]2N',O}tin(IV)

See Mun Lee,a Hapipah Mohd Ali,a Kong Mun Loa and Seik Weng Nga*

aDepartment of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia
Correspondence e-mail: seikweng@um.edu.my

In the title compound, [Sn(C6H11)2(C19H14N2O3)], the SnIV atom is O,N,O' chelated by the deprotonated Schiff base ligand and exists in a cis-trigonal-bipyramidal environment, completed by the two cyclohexyl ligands.

Related literature

For other dialkyltin(IV) compounds with similar Schiff-base ligands, see: Lee et al. (2009a[Lee, S. M., Lo, K. M., Mohd Ali, H. & Ng, S. W. (2009a). Acta Cryst. E65, m816.],b[Lee, S. M., Lo, K. M., Ali, H. M. & Ng, S. W. (2009b). Acta Cryst. E65, m862.],c[Lee, S. M., Lo, K. M., Ali, H. M. & Ng, S. W. (2009c). Acta Cryst. E65, m863.]).

[Scheme 1]

Experimental

Crystal data

  • [Sn(C6H11)2(C19H14N2O3)]

  • Mr = 603.31

  • Monoclinic, C 2/c

  • a = 30.2358 (4) Å

  • b = 7.7030 (1) Å

  • c = 25.8528 (4) Å

  • [beta] = 111.249 (2)°

  • V = 5611.92 (16) Å3

  • Z = 8

  • Mo K[alpha] radiation

  • [mu] = 0.95 mm-1

  • T = 293 K

  • 0.30 × 0.10 × 0.10 mm
Data collection

  • Bruker SMART APEX diffractometer

  • Absorption correction: multi-scan (SADABS; Sheldrick, 1996[Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany.]) Tmin = 0.765, Tmax = 0.912

  • 26097 measured reflections

  • 6424 independent reflections

  • 3942 reflections with I > 2[sigma](I)

  • Rint = 0.047
Refinement

  • R[F2 > 2[sigma](F2)] = 0.043

  • wR(F2) = 0.111

  • S = 1.00

  • 6424 reflections

  • 336 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.52 e Å-3

  • [Delta][rho]min = -0.43 e Å-3

Data collection: APEX2 (Bruker, 2009[Bruker (2009). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2009[Bruker (2009). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: X-SEED (Barbour, 2001[Barbour, L. J. (2001). J. Supramol. Chem. 1, 189-191.]); software used to prepare material for publication: publCIF (Westrip, 2010[Westrip, S. P. (2010). publCIF. In preparation.]).

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: CI5035 ).

Acknowledgements

The authors thank the University of Malaya (RG020/09AFR) for supporting this study.

References

Barbour, L. J. (2001). J. Supramol. Chem. 1, 189-191.  [CrossRef] [ChemPort]
Bruker (2009). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Lee, S. M., Lo, K. M., Mohd Ali, H. & Ng, S. W. (2009a). Acta Cryst. E65, m816.  [CSD] [CrossRef] [details]
Lee, S. M., Lo, K. M., Ali, H. M. & Ng, S. W. (2009b). Acta Cryst. E65, m862.  [CSD] [CrossRef] [details]
Lee, S. M., Lo, K. M., Ali, H. M. & Ng, S. W. (2009c). Acta Cryst. E65, m863.  [CSD] [CrossRef] [details]
Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Westrip, S. P. (2010). publCIF. In preparation.

Acta Cryst (2010). E66, m309  [ doi:10.1107/S1600536810005829 ]

This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.