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Acta Cryst. (2010). E66, m248  [ doi:10.1107/S1600536810003338 ]

Azido(benzoylacetonato-[kappa]2O,O')[1-phenyl-3-(2-pyridylmethylimino)but-1-en-1-olato-[kappa]3N,N',O]cobalt(III)

A. Datta, M.-H. Sie, J.-H. Huang and H. M. Lee

Abstract: In the title complex, [Co(C16H15N2O)(C10H9O2)(N3)], the CoII atom adopts an octahedral coordination geometry by a tridentate Schiff base, a bidentate benzoylacetonate and an azide ligand. The imine N atom of the tridentate ligand is trans to the benzoyl O atom of the bidentate ligand and the azide ligand is trans to the acetyl O atom of the bidentate ligand. Non-classical intramolecular Caryl-H...O hydrogen bonds are present in the structure.

Online 3 February 2010


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