Acta Cryst. (2010). E66, m259-m260 [ doi:10.1107/S160053681000406X ]
Abstract: In the title compound, [Ag(C8H5O7S)(C10H8N2)]n, the Ag atom is tetracoordinated by two 4,4'-bipydidine (4,4'-bipy) N atoms and two monodentate sulfonate O atoms of the 5-sulfoisophthalic acid (H3sip) ligands. Adjacent Ag atoms are bonded through four sulfonate O atoms, forming a dinuclear unit with an AgAg separation of 3.384 (5) Å; they are further linked together by the 4,4'-bipy lignds into a chain. Classical intermolecular O-HO and non-classical intramolecular C-HO hydrogen bonds are also observed in the two-dimensional supramolecuar structure.
Online 6 February 2010
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