Acta Cryst. (2010). E66, m481  [ doi:10.1107/S1600536810011372 ]

(4-Methylbenzohydrazidato-²N',O)[2-(4-methylbenzoylhydrazinylidene-²N,O)-3-phenylpropionato(2-)]oxidovanadium(V) methanol monosolvate

H. W. Wong, K. M. Lo and S. W. Ng

Abstract: The V^V atom in the title compound, [V(C₈H₉N₂O)(C₁₇H₁₄N₂O₃)O]·CH₃OH, is N,O-chelated by the benzoylhydrazidate anion and O,N,O'-chelated by the (benzoylhydrazono)propionate dianion. The octahedral trans-N₂O₄ coordination geometry is completed by the vanadyl O atom. Two mononuclear complexes and two solvent molecules are linked by O-HO and O-HN hydrogen bonds, generating a centrosymmetric aggregate.

Online 31 March 2010

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