Received 25 March 2010
The VV atom in the title compound, [V(C8H9N2O)(C17H14N2O3)O]·CH3OH, is N,O-chelated by the benzoylhydrazidate anion and O,N,O'-chelated by the (benzoylhydrazono)propionate dianion. The octahedral trans-N2O4 coordination geometry is completed by the vanadyl O atom. Two mononuclear complexes and two solvent molecules are linked by O-HO and O-HN hydrogen bonds, generating a centrosymmetric aggregate.
For (benzohydrazidato)[2-(benzoylhydrazono)propionato]oxidovanadium(V), see: Wong et al. (2009a) and for (4-chlorobenzohydrazidato)[2-(4-chlorobenzoylhydrazono)propionato(2-)]oxidovanadium(V), see: Wong et al. (2009,b).
Data collection: APEX2 (Bruker, 2009); cell refinement: SAINT (Bruker, 2009); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: X-SEED (Barbour, 2001); software used to prepare material for publication: publCIF (Westrip, 2010).
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: BT5227 ).
We thank the University of Malaya (RG020/09AFR) for supporting this study.
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