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Volume 66 
Part 4 
Page m420  
April 2010  

Received 14 March 2010
Accepted 15 March 2010
Online 20 March 2010

Key indicators
Single-crystal X-ray study
T = 223 K
Mean [sigma](C-C) = 0.008 Å
R = 0.039
wR = 0.087
Data-to-parameter ratio = 22.4
Details
Open access

[(Z)-O-Isopropyl N-(4-chlorophenyl)thiocarbamato-[kappa]S](tricyclohexylphosphine-[kappa]P)gold(I)

aDepartment of Chemistry, National University of Singapore, Singapore 117543, and bDepartment of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia
Correspondence e-mail: edward.tiekink@gmail.com

The Au atom in the title compound, [Au(C10H11ClNOS)(C18H33P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 172.45 (5)°], with the distortion due in part to a close intramolecular Au...O contact [3.134 (3) Å].

Related literature

For the structural systematics and luminescence properties of phosphinegold(I) carbonimidothioates, see: Ho et al. (2006[Ho, S. Y., Cheng, E. C.-C., Tiekink, E. R. T. & Yam, V. W.-W. (2006). Inorg. Chem. 45, 8165-8174.]); Ho & Tiekink (2007[Ho, S. Y. & Tiekink, E. R. T. (2007). CrystEngComm, 9, 368-378.]); Kuan et al. (2008[Kuan, F. S., Ho, S. Y., Tadbuppa, P. P. & Tiekink, E. R. T. (2008). CrystEngComm, 10, 548-564.]). For the synthesis, see Hall et al. (1993[Hall, V. J., Siasios, G. & Tiekink, E. R. T. (1993). Aust. J. Chem. 46, 561-570.]).

[Scheme 1]

Experimental

Crystal data
  • [Au(C10H11ClNOS)(C18H33P)]

  • Mr = 706.09

  • Monoclinic, P 21 /c

  • a = 9.4547 (15) Å

  • b = 26.137 (4) Å

  • c = 12.326 (2) Å

  • [beta] = 100.162 (3)°

  • V = 2998.0 (8) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 5.14 mm-1

  • T = 223 K

  • 0.32 × 0.07 × 0.07 mm

Data collection
  • Bruker SMART CCD diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2000[Bruker (2000). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.466, Tmax = 1.000

  • 20961 measured reflections

  • 6886 independent reflections

  • 5416 reflections with I > 2[sigma](I)

  • Rint = 0.037

Refinement
  • R[F2 > 2[sigma](F2)] = 0.039

  • wR(F2) = 0.087

  • S = 1.06

  • 6886 reflections

  • 307 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 3.49 e Å-3

  • [Delta][rho]min = -1.06 e Å-3

Table 1
Selected bond lengths (Å)

Au-P1 2.2646 (12)
Au-S1 2.3027 (13)

Data collection: SMART (Bruker, 2000[Bruker (2000). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2000[Bruker (2000). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: PATTY in DIRDIF92 (Beurskens et al., 1992[Beurskens, P. T., Admiraal, G., Beurskens, G., Bosman, W. P., Garcia-Granda, S., Gould, R. O., Smits, J. M. M. & Smykalla, C. (1992). The DIRDIF Program System. Technical Report. Crystallography Laboratory, University of Nijmegen, The Netherlands.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: ORTEP-3 (Farrugia, 1997[Farrugia, L. J. (1997). J. Appl. Cryst. 30, 565.]) and DIAMOND (Brandenburg, 2006[Brandenburg, K. (2006). DIAMOND. Crystal Impact GbR, Bonn, Germany.]); software used to prepare material for publication: publCIF (Westrip, 2010[Westrip, S. P. (2010). publCIF. In preparation.]).


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: HG2659 ).


Acknowledgements

The National University of Singapore (grant No. R-143-000-213-112) is thanked for support.

References

Beurskens, P. T., Admiraal, G., Beurskens, G., Bosman, W. P., Garcia-Granda, S., Gould, R. O., Smits, J. M. M. & Smykalla, C. (1992). The DIRDIF Program System. Technical Report. Crystallography Laboratory, University of Nijmegen, The Netherlands.
Brandenburg, K. (2006). DIAMOND. Crystal Impact GbR, Bonn, Germany.
Bruker (2000). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Farrugia, L. J. (1997). J. Appl. Cryst. 30, 565.  [CrossRef] [details]
Hall, V. J., Siasios, G. & Tiekink, E. R. T. (1993). Aust. J. Chem. 46, 561-570.  [ChemPort]
Ho, S. Y., Cheng, E. C.-C., Tiekink, E. R. T. & Yam, V. W.-W. (2006). Inorg. Chem. 45, 8165-8174.  [ISI] [CSD] [CrossRef] [PubMed] [ChemPort]
Ho, S. Y. & Tiekink, E. R. T. (2007). CrystEngComm, 9, 368-378.  [ISI] [CSD] [CrossRef] [ChemPort]
Kuan, F. S., Ho, S. Y., Tadbuppa, P. P. & Tiekink, E. R. T. (2008). CrystEngComm, 10, 548-564.  [ISI] [CSD] [CrossRef] [ChemPort]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Westrip, S. P. (2010). publCIF. In preparation.


Acta Cryst (2010). E66, m420  [ doi:10.1107/S1600536810009736 ]

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