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Acta Cryst. (2010). E66, o883  [ doi:10.1107/S1600536810009773 ]

(E)-2-[1-(3-Amino-4-chlorophenylimino)ethyl]-4-bromophenol

H. Bahron, S. N. A. Bakar, K. Kassim, C. S. Yeap and H.-K. Fun

Abstract: The title Schiff base compound, C14H12BrClN2O, exists in an E configuration with respect to the central C=N double bond. The amino group adopts a pyramidal configuration. The dihedral angle between the two benzene rings is 76.88 (10)° and an intramolecular O-H...N hydrogen bond forms a six-membered ring, generating an S(6) ring motif. In the crystal structure, molecules are linked into chains along [010] via N-H...O hydrogen bonds. The presence of [pi]-[pi] interactions [centroid-centroid distance = 3.6244 (12) Å] further stabilizes the crystal structure.

Online 20 March 2010


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