Acta Cryst. (2010). E66, m498  [ doi:10.1107/S160053681001189X ]

[O-Ethyl (Z)-N-(2-chlorophenyl)thiocarbamato-S](tricyclohexylphosphine-P)gold(I)

P. P. Tadbuppa and E. R. T. Tiekink

Abstract: The title compound, [Au(C₉H₉ClNOS)(C₁₈H₃₃P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S,P-donor set [S-Au-P = 177.62 (5)°]. The distortion is ascribed to the close approach of the O atom, which forms an intramolecular contact of 2.970 (5) Å. Disorder was found in the structure with two positions of equal weight being resolved for the C atoms comprising the ethoxy group.

Online 10 April 2010

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