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Acta Cryst. (2010). E66, m578  [ doi:10.1107/S1600536810014753 ]

catena-Poly[[(acetato-[kappa]2O,O')(methanol-[kappa]O)cadmium(II)]-[mu]-[1,2-bis(1H-benzimidazol-2-yl)ethane]-[kappa]2N3:N3'-[(acetato-[kappa]2O,O')(methanol-[kappa]O)cadmium(II)]-di-[mu]-chlorido]

H.-X. Yang, J. Zhang, Y.-N. Ding and X.-R. Meng

Abstract: In the title complex, [Cd2(CH3COO)2Cl2(C16H14N4)(CH3OH)2]n, the CdII atom is six-coordinated by one N atom from a centrosymmetric bridging 1,2-bis(2,2'-1H-benzimidazol-2-yl)ethane (bbe) ligand, two O atoms from a chelating acetate ligand, one O atom from a methanol molecule and two bridging Cl atoms in a distorted octahedral geometry. The CdII atoms are connected alternately by the Cl atoms and bbe ligands, leading to a chain along [001]. These chains are further linked by O-H...O hydrogen bonds. Intrachain N-H...O hydrogen bonds are observed.

Online 28 April 2010


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