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Acta Cryst. (2010). E66, m632  [ doi:10.1107/S1600536810016442 ]

Hexakis(dimethylammonium) di-[mu]6-oxido-tetra-[mu]3-oxido-tetradeca-[mu]2-oxido-octaoxidodecavanadate(V) monohydrate

S. Wang, L. Lu, S. Feng and M. Zhu

Abstract: In the title compound, (C2H8N)6[V10O28]·H2O, the [V10O28]6- polymetalate anion has crystallographic mirror symmetry with six V atoms and 12 O atoms lying on the mirror plane. Each of the VV atoms adopts a distorted octahedral geometry. Eight terminal O atoms are bonded to VV atoms with double bonds and the others act as bridging atoms. In the crystal structure, a network of N-H...O and O-H...O hydrogen bonds helps to establish the packing.

Online 8 May 2010


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