(3,4-Dimeth­oxy­phen­yl)(4-fluoro­phen­yl)methanone

Lv, Q.; Wang, J.

doi:10.1107/S1600536810021008

Volume 66
Part 7
Page o1585
July 2010

Received 22 May 2010
Accepted 2 June 2010
Online 5 June 2010

Key indicators
Single-crystal X-ray study
T = 298 K
Mean (C-C) = 0.004 Å
R = 0.056
wR = 0.173
Data-to-parameter ratio = 12.8
Details

(3,4-Dimethoxyphenyl)(4-fluorophenyl)methanone

Quanjian Lv ^a ^* and Jianling Wang ^a

^aDepartment of Quality Detection and Management, Zhengzhou College of Animal Husbandry Engineering, Zhengzhou 450011, People's Republic of China
Correspondence e-mail: jyzhang2004@126.com

In the title compound, C₁₅H₁₃FO₃, the dihedral angle between the two aromatic rings is 52.78 (8)°. In the crystal, intermolecular C-HO hydrogen bonds link molecules into chains running parallel to the c axis.

Related literature

For applications of benzophenone and its derivatives, see: Riechers et al. (1996); Khanum et al. (2009); Schlecht et al. (2008).

Experimental

Crystal data

C₁₅H₁₃FO₃
M_r = 260.25
Monoclinic, P 2₁ /c
a = 10.8926 (9) Å
b = 11.3632 (11) Å
c = 10.8369 (10) Å
= 108.285 (1)°
V = 1273.6 (2) Å³
Z = 4
Mo K radiation
= 0.10 mm^-1
T = 298 K
0.48 × 0.38 × 0.15 mm

Data collection

Bruker SMART CCD area-detector diffractometer
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) T_min = 0.952, T_max = 0.985
6183 measured reflections
2227 independent reflections
1391 reflections with I > 2(I)
R_int = 0.083

Refinement

R[F² > 2(F²)] = 0.056
wR(F²) = 0.173
S = 1.00
2227 reflections
174 parameters
H-atom parameters constrained
_max = 0.20 e Å^-3
_min = -0.32 e Å^-3

Table 1
Hydrogen-bond geometry (Å, °)

D-HA	D-H	HA	DA	D-HA
C7-H7O1ⁱ	0.93	2.58	3.343 (3)	139
Symmetry code: (i) $[x, -y+{\script{3\over 2}}, z-{\script{1\over 2}}]$ .

Data collection: SMART (Siemens, 1996); cell refinement: SAINT (Siemens, 1996); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: RZ2456 ).

Acknowledgements

We gratefully acknowledge financial support from the National Natural Science Foundation of China (No. 20572103).

References

Khanum, S. A., Girish, V., Suparshwa, S. S., Khanum, N. F. (2009). Bioorg. Med. Chem. Lett. 19, 1887-1891.
Riechers, H., Albrecht, H.-P. & Amberg, W. (1996). J. Med. Chem. 39, 2123-2128..
Schlecht, C., Klammer, H., Frauendorf, H., Wuttke, W. & Jarry, H. (2008). Toxicology, 245, 11-17.
Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.
Siemens (1996). SMART and SAINT. Siemens Analytical X-ray Instruments Inc., Madison, Wisconsin, USA.

organic compounds