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Acta Cryst. (2010). E66, m993  [ doi:10.1107/S1600536810028448 ]

Dibromido[1,1'-dibenzyl-2,2'-(sulfanediyldimethylene)di-1H-benzimidazole]cadmium(II) dimethylformamide solvate

K. Wang, J. Yuan, G. Chen, Q. Chen and H. Wu

Abstract: In the title compound, [CdBr2(C30H26N4S)]·C3H7NO, both the complex and solvent molecule lie on a crystallographic mirror plane. The CdII ion is coordinated in a disorted square-pyramidal CdBr2N2S environment with one of the Br atoms in the apical site. In the crystal structure, the benzimidazole ring systems are involved in weak intermolecular [pi]-[pi] stacking interactions [centroid-centroid distances = 3.606 (2) and 3.753 (2) Å]. Further stabilization is provided by weak intermolecular C-H...O hydrogen bonds. The methyl H atoms of the dimethylformamide solvent molecule are disordered about a mirror plane.

Online 21 July 2010


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