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Acta Cryst. (2010). E66, m1042-m1043  [ doi:10.1107/S160053681002893X ]

Tetraethylammonium tricarbonylchlorido(quinoxaline-2-carboxylato-[kappa]2N1,O)rhenate(I)

J. Suthiram, J. R. Zeevaart, H. G. Visser and A. Roodt

Abstract: In the title compound, (C8H20N)[Re(C9H5N2O2)Cl(CO)3], the ReI atom is coordinated facially by three carbonyl groups, the bidentate quinoxaline-2-carbaldehyde ligand and a chloride atom, forming a distorted octahedral geometry.. The crystal packing is controlled by C-H...O hydrogen bonding and [pi]-[pi] stacking interactions involving the benzene rings, with a centroid-centroid distance of 3.4220 (1) Å.

Online 31 July 2010


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