(Methanol-κO)(perchlorato-κO)bis­(triphenyl­phosphine-κP)silver(I)

Cui, L.-N.; Jin, Q.-H.; Hu, K.-Y.; Zhang, C.-L.

doi:10.1107/S160053681002814X

Volume 66
Part 8
Page m969
August 2010

Received 22 June 2010
Accepted 14 July 2010
Online 21 July 2010

Key indicators
Single-crystal X-ray study
T = 298 K
Mean (C-C) = 0.008 Å
R = 0.040
wR = 0.103
Data-to-parameter ratio = 14.6
Details

(Methanol-O)(perchlorato-O)bis(triphenylphosphine-P)silver(I)

Li-Na Cui,^a Qiong-Hua Jin,^a ^* Ke-Yi Hu ^a and Cun-Lin Zhang ^b

^aDepartment of Chemistry, Capital Normal University, Beijing 100048, People's Republic of China, and ^bBeijing Key Laboratory for Terahertz Spectroscopy and Imaging, Key Laboratory of Terahertz Optoelectronics, Ministry of Education, Capital Normal University, Beijing 100048, People's Republic of China
Correspondence e-mail: jinqh204@163.com

In the title complex, [Ag(ClO₄)(CH₃OH)(C₁₈H₁₅P)₂], the angles around the central Ag⁺ ion indicate that it is in a distorted tetrahedral coordination. The coordination sphere of silver is formed by two P atoms of two triphenylphosphine ligands, one O atom of a perchlorate anion and one O atom of a methanol molecule. The crystal structure is stablized by a bifurcated intermolecular O-HO hydrogen bond, involving the O-H donor from methanol and two acceptor O atoms from the perchlorate anion, so forming a zigzag chain propagating in [010].

Related literature

For related structures, see: Cui et al. (2010); Cingolani et al. (2002); Nicola et al. (2007); Pettinari et al. (2007); Effendy et al. (2007a,b); Awaleh et al. (2005); Balakrishna et al. (2009). For general backgound to the structural chemistry of silver(I) complexes with ligands containing phosphine groups and nitrogen atoms, see: Jin et al. (2010); Wu et al. (2009).

Experimental

Crystal data

[Ag(ClO₄)(CH₄O)(C₁₈H₁₅P)₂]
M_r = 763.90
Monoclinic, P 2₁ /n
a = 13.6426 (15) Å
b = 12.8444 (14) Å
c = 19.714 (2) Å
= 92.602 (1)°
V = 3450.9 (7) Å³
Z = 4
Mo K radiation
= 0.80 mm^-1
T = 298 K
0.33 × 0.22 × 0.14 mm

Data collection

Bruker SMART CCD area-detector diffractometer
Absorption correction: multi-scan (SADABS; Bruker, 2007) T_min = 0.779, T_max = 0.897
17113 measured reflections
6073 independent reflections
3802 reflections with I > 2(I)
R_int = 0.040

Refinement

R[F² > 2(F²)] = 0.040
wR(F²) = 0.103
S = 1.08
6073 reflections
415 parameters
H-atom parameters constrained
_max = 0.49 e Å^-3
_min = -0.32 e Å^-3

Table 1
Hydrogen-bond geometry (Å, °)

D-HA	D-H	HA	DA	D-HA
O5-H5O2ⁱ	0.82	2.42	3.157 (6)	151
O5-H5O3ⁱ	0.82	2.30	3.033 (6)	150
Symmetry code: (i) $[-x+{\script{1\over 2}}, y+{\script{1\over 2}}, -z+{\script{1\over 2}}]$ .

Data collection: SMART (Bruker, 2007); cell refinement: SAINT-Plus (Bruker, 2007); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: SU2191 ).

Acknowledgements

This work was supported by the National Keystone Basic Research Program (973 Program) under grants Nos. 2007CB310408 and 2006CB302901, the Funding Project for Academic Human Resources Development in Institutions of Higher Learning under the jurisdiction of Beijing Municipality, and the State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences.

References

Awaleh, M. O., Badia, A. & Brisse, F. (2005). Inorg. Chem. 44, 7833-7845.
Balakrishna, M. S., Venkateswaran, R. & Mobin, S. M. (2009). Inorg. Chim. Acta, 362, 271-276.
Bruker (2007). SMART, SAINT-Plus and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Cingolani, A., Effendy, Pellei, M., Pettinari,C., Santini, C., Skelton, B.W.& White, A.H. (2002). Inorg. Chem. 41, 6633-6645.
Cui, L.-N., Hu, K.-Y., Jin, Q.-H. & Zhang, C.-L. (2010). Acta Cryst. E66, m871.
Effendy, Marchetti, F., Pettinari, C., Pettinari, R., Skelton, B.W. & White, A.H. (2007b). Inorg. Chim. Acta, 360, 1451-1465.
Effendy, Marchetti, F., Pettinari, C., Skelton, B.W.& White, A.H. (2007a). Inorg. Chim. Acta, 360, 1424-1432.
Jin, Q. H., Hu, K. Y., Song, L. L., Wang, R., Zhang, C. L., Zuo, X. & Lu, X. M. (2010). Polyhedron, 29, 441-445.
Nicola, C.D., Effendy, Marchetti, F., Pettinari, C., Skelton, B.W. & White, A.H. (2007). Inorg. Chim. Acta, 360, 1433-1450.
Pettinari, C., Ngoune, J., Skelton, B. W. & White, A. H. (2007). Inorg. Chem. Commun. 10, 329-331.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.
Wu, J.-Q., Jin, Q.-H., Hu, K.-Y. & Zhang, C.-L. (2009). Acta Cryst. E65, m1096-m1097.

metal-organic compounds