[HTML version][PDF version][CIF][3d view][Structure Factors][Supplementary Material][CIF check Report][Issue contents]  [Open access]

[Contents scheme]

Acta Cryst. (2010). E66, o2176-o2177  [ doi:10.1107/S1600536810029600 ]

Epoxycytochalasin H methanol solvate

L. Li, Y. Liu, T. Yang, K. Yu and Q. Zou

Abstract: In the title solvate, C30H39NO5·CH4O {systematic name: 21-acetoxy-18,21-dihydroxy-5,6,16,18-tetramethyl-10-phenyl-6,7-epoxy-[11]cytochalasa-13,19-dien-1-one methanol solvate}, the organic molecule exhibits the tetracyclic terpenoid skeleton of cytochalasin, consisting of fused five-, six-, three- and 11-membered rings. The five-membered ring adopts an envelope conformation, while the six-membered ring is in a boat conformation. The epoxy O atom on the six-membered ring is pointing away from the five-membered ring. An interstitial methanol solvent molecule is hydrogen bonded to the cytochalasin molecules and intermolecular O-H...O and N-H...O hydrogen bonds connect the molecules into infinite chains along the (\\overline{1}10) direction.

Online 31 July 2010


Copyright © International Union of Crystallography
IUCr Webmaster