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Acta Cryst. (2010). E66, o2584  [ doi:10.1107/S1600536810036639 ]

(1S,2S,6S,9S)-6-Methyl-5-oxobicyclo[4.4.0]decane-2,9-diyl diacetate

R. Aav, K. Lippur, M. Lopp and F. Werner

Abstract: The chiral title compound, C15H22O5, is an intermediate in the total synthesis of biologically active 9,11-secosterols. In the crystal, the cyclohexane rings are trans-fused and both adopt chair conformations. In the crystal, molecules are loosely held together in a layer parallel to (100) by weak intermolcular C-H...O hydrogen bonds accepted by carbonyl O atoms of the acetyl groups.

Online 18 September 2010


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