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Acta Cryst. (2010). E66, m1264  [ doi:10.1107/S1600536810036299 ]

([eta]5-Pentamethylcyclopentadienyl)([eta]6-toluene)ruthenium(II) hexafluoridophosphate

W. W. N. O, A. J. Lough and R. H. Morris

Abstract: In the title complex, [Ru(C7H8)(C10H15)]PF6, the cation lies on a mirror plane and the anion lies on an inversion center. The distance between the Ru atom and the centroid of the benzene ring is 1.706 (5) Å and the distance between the Ru atom and the cyclopentadienyl ring is 1.811 (5) Å. The crystal structure is stabilized by weak C-H...F hydrogen bonds. The H atoms of the methyl groups which lie on the mirror plane are disordered over two sites with equal occupancies.

Online 15 September 2010


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