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Acta Cryst. (2010). E66, m1439  [ doi:10.1107/S1600536810039516 ]

Bis[N'-(2-oxo-1H-indol-3-ylidene)furan-2-carbohydrazidato-[kappa]3O,N',O']manganese(II) N,N-dimethylformide monosolvate monohydrate

S. N. Abdul Halim, H. M. Ali and S. W. Ng

Abstract: In the title compound, [Mn(C13H8N3O3)2]·C3H7NO·H2O, the metal atom is O,N,O'-chelated by two deprotonated Schiff bases and exists in a distorted octahedral geometry. The N-H groups, the carbonyl group of the DMF molecule and the uncoordinated water molecule engage in N-H...O and O-H...O hydrogen-bonding interactions, generating a hydrogen-bonded ribbon that propagates along [110].

Online 23 October 2010


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