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Acta Cryst. (2010). E66, o2820-o2821  [ doi:10.1107/S1600536810040614 ]

(2-Hydroxy-7-methoxynaphthalen-1-yl)(4-methylphenyl)methanone

A. Nagasawa, R. Mitsui, A. Okamoto and N. Yonezawa

Abstract: In the title compound, C19H16O3, an intramolecular O-H...O=C hydrogen bond is formed between the hydroxy and carbonyl groups on the naphthalene ring system, resulting in an S(6) ring. The angles between the C=O bond vector and the least-squares planes of the naphthalene ring system and the benzene ring are 27.63 (6) and 47.99 (7)°, respectively. The dihedral angle between the latter planes is 61.39 (5)°. In the crystal, two molecules are connected by pairs of intermolecular O-H...O=C hydrogen bonds, forming centrosymmetric dimers with an R22(4) graph-set motif. The molecular packing features C-H...[pi] interactions.

Online 20 October 2010


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