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Acta Cryst. (2010). E66, m1431-m1432  [ doi:10.1107/S1600536810041139 ]

catena-Poly[[[tetraaqua(3,5-dinitro-4-oxidopyridine N-oxide-[kappa]O1)neodymium(III)]-[mu]-oxalato-[kappa]4O1,O2:O1',O2'] tetrahydrate]

Y.-F. Han and S. W. Ng

Abstract: In the title coordination polymer, {[Nd(C5H2N3O6)(C2O4)(H2O)4]·4H2O}n, the oxalate dianions link adjacent nine-coordinate, tricapped trigonal-prismatic Nd(III) atoms into a chain running along the b axis. The 3,5-dinitropyridin-4-oxido N-oxide ligand is formally a zwitterionic anion; the anion binds to the metal atom through the N-oxide O atom. The chains are connected into a three-dimensional network by O-H...O hydrogen bonds involving the coordinated and uncoordinated water molecules.

Online 23 October 2010


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