Chloridobis(1,10-phenanthroline)zinc(II) tetra­chlorido(1,10-phenan­throline)bis­muthate(III) monohydrate

Song, C.; Chai, W.; Song, L.; Yang, Y.; Lin, J.

doi:10.1107/S1600536810052682

Volume 67
Part 1
Pages m109-m110
January 2011

Received 19 November 2010
Accepted 15 December 2010
Online 24 December 2010

Key indicators
Single-crystal X-ray study
T = 293 K
Mean (C-C) = 0.003 Å
H completeness 93%
R = 0.024
wR = 0.061
Data-to-parameter ratio = 18.0
Details

Chloridobis(1,10-phenanthroline)zinc(II) tetrachlorido(1,10-phenanthroline)bismuthate(III) monohydrate

Chunlei Song,^a Wenxiang Chai,^a ^* Li Song,^b Yunyun Yang ^a and Jian Lin ^a

^aCollege of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, People's Republic of China, and ^bDepartment of Chemistry, Key Laboratory of Advanced Textile Materials and Manufacturing Technology of the Education Ministry, Zhejiang Sci-Tech University, Hangzhou 310018, People's Republic of China
Correspondence e-mail: wxchai_cm@yahoo.com.cn

In the crystal structure of the title monohydrate salt, [ZnCl(C₁₂H₈N₂)₂][BiCl₄(C₁₂H₈N₂)]·H₂O, the ionic components are linked into three-dimensional supramolecular channels by five pairs of C-HCl hydrogen bonds and [pi] - [pi] stacking interactions with an interplanar distance of 3.643 (2) Å. The solvent water molecules are lodged in the channels.

Related literature

For related bismuth compounds, see: James et al. (2000); Jarraya et al. (1995); Bowmaker et al. (1998). For a related [Zn(phen)₂Cl]⁺ coordinated cation structure, see: Yu & Zhang (2006). For supramolecular systems containing halometallate groups as their main component, see: Mitzi & Brock (2001); Zhu et al. (2003); Papavassiliou et al. (1995); Pohl et al. (1994); Carmalt et al. (1995). For [pi] - [pi] interactions, see: Chandrasekhar et al. (2006). For hydrogen bonds, see: Desiraju & Steiner (1999).

Experimental

Crystal data

[ZnCl(C₁₂H₈N₂)₂][BiCl₄(C₁₂H₈N₂)]·H₂O
M_r = 1010.25
Triclinic, $[P \overline 1]$
a = 9.748 (2) Å
b = 13.694 (4) Å
c = 14.249 (4) Å
= 86.848 (7)°
= 74.660 (5)°
= 80.692 (7)°
V = 1810.0 (8) Å³
Z = 2
Mo K radiation
= 5.93 mm^-1
T = 293 K
0.40 × 0.30 × 0.30 mm

Data collection

Rigaku R-AXIS RAPID diffractometer
Absorption correction: multi-scan (ABSCOR; Higashi, 1995) T_min = 0.200, T_max = 0.269
13923 measured reflections
8140 independent reflections
7571 reflections with I > 2(I)
R_int = 0.012

Refinement

R[F² > 2(F²)] = 0.024
wR(F²) = 0.061
S = 1.03
8140 reflections
451 parameters
H-atom parameters constrained
_max = 1.76 e Å^-3
_min = -1.03 e Å^-3

Table 1
Hydrogen-bond geometry (Å, °)

D-HA	D-H	HA	DA	D-HA
C2-H2Cl3ⁱ	0.93	2.82	3.588 (4)	141
C6-H6Cl4ⁱⁱ	0.93	2.82	3.637 (4)	147
C10-H10Cl5ⁱⁱⁱ	0.93	2.80	3.707 (4)	164
C15-H15Cl1^iv	0.93	2.69	3.579 (4)	160
C25-H25Cl2^v	0.93	2.80	3.506 (4)	134
Symmetry codes: (i) -x+1, -y+1, -z; (ii) -x, -y+1, -z; (iii) x-1, y, z; (iv) -x+2, -y+1, -z; (v) -x+1, -y+1, -z+1.

Data collection: PROCESS-AUTO (Rigaku, 1998); cell refinement: PROCESS-AUTO; data reduction: CrystalStructure (Rigaku/MSC, 2004); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL and PLATON (Spek, 2009).

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: BG2383 ).

Acknowledgements

We are grateful for financial support from the National Natural Science Foundation of China (project 20803070) and the Natural Science Foundation of Zhejiang Province (project Y4100610).

References

Bowmaker, G. A., Junk, P. C., Lee, A. M., Skelton, B. W. & White, A. H. (1998). Aust. J. Chem. 51, 317-324.
Carmalt, C. J., Farrugia, L. J. & Norman, N. C. (1995). Z. Anorg. Allg. Chem. 621, 47-56.
Chandrasekhar, V., Thilagar, P., Steiner, A. & Bickley, J. F. (2006). Chem. Eur. J. 12, 8847-8861.
Desiraju, G. R. & Steiner, T. (1999). The Weak Hydrogen Bond, pp. 86-89. Oxford University Press.
Higashi, T. (1995). ABSCOR. Rigaku Corporation, Tokyo, Japan.
James, S. C., Lawson, Y. G., Norman, N. C., Orpen, A. G. & Quayle, M. J. (2000). Acta Cryst. C56, 427-429.
Jarraya, S., Ben Hassen, R., Daoud, A. & Jouini, T. (1995). Acta Cryst. C51, 2537-2538.
Mitzi, D. B. & Brock, P. (2001). Inorg. Chem. 40, 2096-2104.
Papavassiliou, G. C., Koutselas, I. B., Terzis, A. & Raptopolou, C. P. (1995). Z. Naturforsch. Teil B, 50, 1566-1569.
Pohl, S., Peter, M., Haase, D. & Saak, W. (1994). Z. Naturforsch. Teil B, 49, 741-746.
Rigaku (1998). PROCESS-AUTO. Rigaku Corporation, Tokyo, Japan.
Rigaku/MSC (2004). CrystalStructure. Rigaku/MSC, The Woodlands, Texas, USA.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.
Spek, A. L. (2009). Acta Cryst. D65, 148-155.
Yu, C.-H. & Zhang, R.-C. (2006). Acta Cryst. E62, m1758-m1759.
Zhu, X.-H., Mercier, N., Frere, P., Blanchard, P., Roncali, J., Allain, M., Pasquier, C. & Riou, A. (2003). Inorg. Chem. 42, 5330-5339.