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Acta Cryst. (2011). E67, o87-o88  [ doi:10.1107/S160053681005110X ]

Bis(2,9-dimethyl-1,10-phenanthrolin-1-ium) hydrogen (S,S)-tartrate nonahydrate

Z. Derikvand and M. M. Olmstead

Abstract: The asymmetric unit of the title compound, 2C14H13N2+·2C4H5O6-·9H2O, contains two cations and two anions in addition to nine molecules of water. Each of the hydrogen tartrate anions is hydrogen bonded to itself by translation along [100] in a head-to-tail fashion via a short hydrogen bond with donor-acceptor distances of 2.473 (4) and 2.496 (4) Å. A large number of intermolecular O-H...O, N-H...O and C-H...O hydrogen-bonding interactions, as well as [pi]-[pi] stacking [centroid-centroid distances in the range 3.642 (3) to 3.866 (3) Å], play an important role in the crystal structure.

Online 11 December 2010


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