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Acta Cryst. (2011). E67, o155  [ doi:10.1107/S1600536810051998 ]

(4-Chlorophenyl)(2,7-dimethoxy-8-nitronaphthalen-1-yl)methanone

T. Nishijima, A. Nagasawa, T. Takada, A. Okamoto and N. Yonezawa

Abstract: In the title compound, C19H14ClNO5, the aroyl group is attached to the naphthalene ring system with a non-coplanar configuration. The dihedral angle between naphthalene ring system and benzene ring is 70.62 (6)°. The nitro group is oriented in parallel with the adjacent carbonyl plane. The torsion angle of the carbonyl group and naphthalene ring is 54.68 (19)° (C-C-C-O), and that of nitro group and naphthalene ring is 54.26 (18)° (O-N-C-C). In the crystal, [pi]-[pi] interactions between naphthalene systems [centroid-centroid distances = 3.5633 (9), 3,5634 (9), and 3.9758(9) Å], C-H...O hydrogen bonds, intermolecular N-O...Cl interactions [2.9937 (12) Å] and C-H...[pi] contacts are observed.

Online 18 December 2010


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