Acta Cryst. (2011). E67, o293-o294 [ doi:10.1107/S1600536811000481 ]
Abstract: In the title compound, C16H14N4O4S·H2O, the benzene and pyridine rings make a dihedral angle of 85.8 (1)°. Both enantiomers of the chiral title compound are statistically disordered over the same position in the unit cell. The methyl and carbonyl group attached to the stereogenic center (C5 of the thiazolidine ring) were therefore refined with common site-occupation factors of 0.531 (9) and 0.469 (9), respectively, for each stereoisomer. In the crystal, intermolecular N-HO, O-HO and O-HN hydrogen bonds link the molecules, forming a three-dimensional supramolecular network. The crystal structure further shows - stacking interactions [centroid-centroid distance = 3.5063 (13) Å] between the pyridine rings.
Online 8 January 2011
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