Received 30 December 2010
In the title complex, [Co(NCS)2(C13H19N3O)(H2O)], the CoII ion is six-coordinated by the N,N',N''-tridentate Schiff base, the N atoms of two thiocyanate ligands and one water molecule in a distorted octahedral geometry. Intramolecular C-HN and C-HO hydrogen bonds occur. In the crystal, intermolecular O-HO, O-HS, C-HS and SS [3.5546 (18) Å] interactions result in an infinite three-dimensional network.
Data collection: APEX2 (Bruker, 2007); cell refinement: SAINT (Bruker, 2007); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: X-SEED (Barbour, 2001); software used to prepare material for publication: SHELXL97 and publCIF (Westrip, 2010).
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: PV2377 ).
The authors thank the University of Malaya for funding this study (FRGS grant FP004/2010B).
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