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Volume 67 
Part 2 
Page m241  
February 2011  

Received 8 January 2011
Accepted 12 January 2011
Online 22 January 2011

Key indicators
Single-crystal X-ray study
T = 100 K
Mean [sigma](C-C) = 0.007 Å
R = 0.049
wR = 0.130
Data-to-parameter ratio = 18.2
Details
Open access

8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-2-olato-[kappa]2N,O)stannate(IV) methanol disolvate

aDepartment of Chemistry, General Campus, Shahid Beheshti University, Tehran 1983963113, Iran, and bDepartment of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia
Correspondence e-mail: seikweng@um.edu.my

In the reaction of 8-hydroxyquinoline, 2-methyl-8-hydroxyquinoline and stannic chloride, the 2-methyl-8-hydroxyquinoline is protonated, yielding the disolvated title salt, (C10H10NO)[SnCl4(C9H6NO)]·2CH3OH. The SnIV atom in the anion is N,O-chelated by the hydroxyquinolinate in a cis-SnNOCl4 octahedral geometry. In the crystal, the cation, anion and solvent molecules are linked by N-H...O, O-H...O and O-H...Cl hydrogen bonds, generating a three-dimensional network.

Related literature

For related tin-oxinate structures, see: Archer et al. (1987[Archer, S. J., Koch, K. R. & Schmidt, S. (1987). Inorg. Chim. Acta, 126, 209-218.]); Fazaeli et al. (2009[Fazaeli, Y., Najafi, E., Amini, M. M. & Ng, S. W. (2009). Acta Cryst. E65, m270.]); Lo & Ng (2009[Lo, K. M. & Ng, S. W. (2009). Acta Cryst. E65, m719.]).

[Scheme 1]

Experimental

Crystal data
  • (C10H10NO)[SnCl4(C9H6NO)]·2CH4O

  • Mr = 628.91

  • Triclinic, [P \overline 1]

  • a = 7.9395 (3) Å

  • b = 9.9721 (4) Å

  • c = 16.0531 (8) Å

  • [alpha] = 75.056 (4)°

  • [beta] = 82.529 (4)°

  • [gamma] = 88.529 (3)°

  • V = 1217.53 (9) Å3

  • Z = 2

  • Mo K[alpha] radiation

  • [mu] = 1.52 mm-1

  • T = 100 K

  • 0.30 × 0.25 × 0.20 mm

Data collection
  • Agilent SuperNova Dual diffractometer with an Atlas detector

  • Absorption correction: multi-scan (CrysAlis PRO; Agilent Technologies, 2010[Agilent Technologies (2010). CrysAlis PRO. Agilent Technologies, Yarnton, England.]) Tmin = 0.659, Tmax = 0.751

  • 8825 measured reflections

  • 5371 independent reflections

  • 4258 reflections with I > 2[sigma](I)

  • Rint = 0.040

Refinement
  • R[F2 > 2[sigma](F2)] = 0.049

  • wR(F2) = 0.130

  • S = 1.05

  • 5371 reflections

  • 295 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 1.76 e Å-3

  • [Delta][rho]min = -1.85 e Å-3

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
O2-H2...O3 0.84 1.76 2.595 (4) 172
O3-H3...O1 0.84 1.91 2.736 (4) 168
O4-H4...Cl1i 0.84 2.53 3.258 (3) 146
N2-H2n...O4 0.88 1.91 2.764 (5) 162
Symmetry code: (i) x+1, y+1, z.

Data collection: CrysAlis PRO (Agilent Technologies, 2010[Agilent Technologies (2010). CrysAlis PRO. Agilent Technologies, Yarnton, England.]); cell refinement: CrysAlis PRO; data reduction: CrysAlis PRO; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: X-SEED (Barbour, 2001[Barbour, L. J. (2001). J. Supramol. Chem. 1, 189-191.]); software used to prepare material for publication: publCIF (Westrip, 2010[Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.]).


Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: SI2328 ).


Acknowledgements

We thank Shahid Beheshti University and the University of Malaya for supporting this study.

References

Agilent Technologies (2010). CrysAlis PRO. Agilent Technologies, Yarnton, England.
Archer, S. J., Koch, K. R. & Schmidt, S. (1987). Inorg. Chim. Acta, 126, 209-218.  [CrossRef] [ChemPort] [ISI]
Barbour, L. J. (2001). J. Supramol. Chem. 1, 189-191.  [CrossRef] [ChemPort]
Fazaeli, Y., Najafi, E., Amini, M. M. & Ng, S. W. (2009). Acta Cryst. E65, m270.  [CSD] [CrossRef] [details]
Lo, K. M. & Ng, S. W. (2009). Acta Cryst. E65, m719.  [CSD] [CrossRef] [details]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.  [ISI] [CrossRef] [ChemPort] [details]


Acta Cryst (2011). E67, m241  [ doi:10.1107/S1600536811001954 ]

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