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Acta Cryst. (2011). E67, o836  [ doi:10.1107/S1600536811008336 ]

Bis(2-aminopyridinium) 5,5'-disulfanediylbis(1,3,4-thiadiazole-2-thiolate) monohydrate

P. Zhao, Z. Guo and H. Xiao

Abstract: In the crystal of the title compound, 2C5H7N2+·C4N4S62-·H2O, intermolecular N-H...S and N-H...N hydrogen bonds link four cations and two dianions into a centrosymmetric cluster. The crystal packing is further consolidated by [pi]-[pi] interactions between the five- and six-membered rings of neighbouring clusters [centroid-centroid distances = 3.692 (3), 3.718 (3), 3.660 (3) and 3.696 (3) Å] and via O-H...N, O-H...S and N-H...O hydrogen bonds involving the uncoordinated water molecules.

Online 12 March 2011


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