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Volume 67 
Part 4 
Page m479  
April 2011  

Received 23 February 2011
Accepted 17 March 2011
Online 26 March 2011

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Key indicators
Single-crystal X-ray study
T = 296 K
Mean [sigma](C-C) = 0.008 Å
Disorder in main residue
R = 0.026
wR = 0.066
Data-to-parameter ratio = 16.7
Details
Open access

Bis[bis(diphenylthiophosphinyl)amido-[kappa]2S,S']platinum(II)

Cemal Güzelsoylu,a Sevil Irislia* and Orhan Büyükgüngörb

aUniversity of Ege, Faculty of Science, Department of Chemistry, 35100 Izmir, Turkey, and bUniversity of Ondokuzmay, Faculty of Science, Department of Physics, 55139 Samsun, Turkey
Correspondence e-mail: irislisevil@hotmail.com

In the title compound, [Pt(C24H20NP2S2)2], the Pt atom is in a distorted square-planar environment and contains two six-membered carbon-free chelate rings, one in twist-boat and the other in a half-chair conformation. Two phenyl groups are disordered over two set of sites in ratios of 0.721 (13):0.279 (13) and 0.71 (7):0.29 (7).

Related literature

For general background to imidodiphosphinedichalcogenides, see: Schmidpeter & Groger (1966[Schmidpeter, A. & Groger, H. (1966). Z. Anorg. Allg. Chem. 345, 106-118.]); Woollins (1996[Woollins, J. D. (1996). J. Chem. Soc. Dalton Trans. pp. 2893-2901.]); Haiduc (1997[Haiduc, I. (1997). Coord. Chem. Rev. 158, 325-358.]); Silvestru et al. (1998[Silvestru, C., Rösler, R., Drake, J. E., Yang, J. & Espinosa-Pérez, G. (1998). J. Chem. Soc. Dalton Trans. pp. 73-78.]); Sekar & Ibers (2006[Sekar, P. & Ibers, J. A. (2006). Inorg. Chim. Acta, 359, 2751-2755.]); Crouch et al. (2003[Crouch, D. J., Helliwell, M., O'Brien, P., Park, J., Waters, J. & Williams, D. J. (2003). Dalton Trans. pp. 1500-1504.]); Abbati et al. (2001[Abbati, G. L., Aragoni, M. C., Arca, M., Devillanova, F. A., Fabretti, A. C., Garau, A., Isaia, F., Lippolis, V. & Verani, G. (2001). J. Chem. Soc. Dalton Trans. pp. 1105-1110.]). For related structures, see: Yanar et al. (2007[Yanar, S., Irisli, S. & Büyükgüngör, O. (2007). Polyhedron, 26, 4114-4118.]); Bhattacharyya & Woollins (1995[Bhattacharyya, P. & Woollins, J. D. (1995). Polyhedron, 14, 3367-3388.]); Irisli & Yanar (2006[Irisli, S. & Yanar, S. (2006). Polyhedron, 25, 1333-1336.]); Berry et al. (1988[Berry, D. E., Browning, J., Dixon, K. R. & Hilts, R. W. (1988). Can. J. Chem. 66, 1272-1282.]). For geometric analysis, see: Cremer & Pople (1975[Cremer, D. & Pople, J. A. (1975). J. Am. Chem. Soc. 97, 1354-1358.])

[Scheme 1]

Experimental

Crystal data

  • [Pt(C24H20NP2S2)2]

  • Mr = 1092.03

  • Triclinic, [P \overline 1]

  • a = 10.1103 (4) Å

  • b = 10.7023 (4) Å

  • c = 23.9258 (9) Å

  • [alpha] = 98.137 (3)°

  • [beta] = 90.496 (3)°

  • [gamma] = 115.563 (3)°

  • V = 2304.86 (15) Å3

  • Z = 2

  • Mo K[alpha] radiation

  • [mu] = 3.40 mm-1

  • T = 296 K

  • 0.56 × 0.32 × 0.08 mm
Data collection

  • Stoe IPDS 2 diffractometer

  • Absorption correction: integration (X-RED32; Stoe & Cie, 2002[Stoe & Cie (2002). X-AREA and X-RED32. Stoe & Cie, Darmstadt, Germany.]) Tmin = 0.302, Tmax = 0.790

  • 23061 measured reflections

  • 9495 independent reflections

  • 8823 reflections with I > 2[sigma](I)

  • Rint = 0.033
Refinement

  • R[F2 > 2[sigma](F2)] = 0.026

  • wR(F2) = 0.066

  • S = 1.03

  • 9495 reflections

  • 570 parameters

  • 24 restraints

  • H-atom parameters constrained

  • [Delta][rho]max = 0.82 e Å-3

  • [Delta][rho]min = -0.79 e Å-3

Data collection: X-AREA (Stoe & Cie, 2002[Stoe & Cie (2002). X-AREA and X-RED32. Stoe & Cie, Darmstadt, Germany.]); cell refinement: X-AREA; data reduction: X-RED32 (Stoe & Cie, 2002[Stoe & Cie (2002). X-AREA and X-RED32. Stoe & Cie, Darmstadt, Germany.]); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997[Farrugia, L. J. (1997). J. Appl. Cryst. 30, 565.]); software used to prepare material for publication: WinGX (Farrugia, 1999[Farrugia, L. J. (1999). J. Appl. Cryst. 32, 837-838.]).

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: JJ2077 ).

Acknowledgements

We thank Ondokuz Mayis University for their X-ray crystallography support and the Research Foundation of Ege University for funding (2009 FEN 032).

References

Abbati, G. L., Aragoni, M. C., Arca, M., Devillanova, F. A., Fabretti, A. C., Garau, A., Isaia, F., Lippolis, V. & Verani, G. (2001). J. Chem. Soc. Dalton Trans. pp. 1105-1110.
Berry, D. E., Browning, J., Dixon, K. R. & Hilts, R. W. (1988). Can. J. Chem. 66, 1272-1282.  [ChemPort]
Bhattacharyya, P. & Woollins, J. D. (1995). Polyhedron, 14, 3367-3388.  [ChemPort]
Cremer, D. & Pople, J. A. (1975). J. Am. Chem. Soc. 97, 1354-1358.  [CrossRef] [ChemPort] [ISI]
Crouch, D. J., Helliwell, M., O'Brien, P., Park, J., Waters, J. & Williams, D. J. (2003). Dalton Trans. pp. 1500-1504.
Farrugia, L. J. (1997). J. Appl. Cryst. 30, 565.  [CrossRef] [details]
Farrugia, L. J. (1999). J. Appl. Cryst. 32, 837-838.  [CrossRef] [ChemPort] [details]
Haiduc, I. (1997). Coord. Chem. Rev. 158, 325-358.  [ChemPort]
Irisli, S. & Yanar, S. (2006). Polyhedron, 25, 1333-1336.
Schmidpeter, A. & Groger, H. (1966). Z. Anorg. Allg. Chem. 345, 106-118.  [ChemPort]
Sekar, P. & Ibers, J. A. (2006). Inorg. Chim. Acta, 359, 2751-2755.  [ChemPort]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Silvestru, C., Rösler, R., Drake, J. E., Yang, J. & Espinosa-Pérez, G. (1998). J. Chem. Soc. Dalton Trans. pp. 73-78.
Stoe & Cie (2002). X-AREA and X-RED32. Stoe & Cie, Darmstadt, Germany.
Woollins, J. D. (1996). J. Chem. Soc. Dalton Trans. pp. 2893-2901.
Yanar, S., Irisli, S. & Büyükgüngör, O. (2007). Polyhedron, 26, 4114-4118.  [ChemPort]

Acta Cryst (2011). E67, m479  [ doi:10.1107/S1600536811010117 ]

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