Acta Cryst. (2011). E67, m479  [ doi:10.1107/S1600536811010117 ]

Bis[bis(diphenylthiophosphinyl)amido-²S,S']platinum(II)

C. Güzelsoylu, S. Irisli and O. Büyükgüngör

Online 26 March 2011

Key indicators

• Single-crystal X-ray study
• T = 296 K
• Mean (C-C) = 0.008 Å
• Disorder in main residue
• R factor = 0.026
• wR factor = 0.066
• Data-to-parameter ratio = 16.7

checkCIF/PLATON results

No syntax errors found




Alert level B
PLAT230_ALERT_2_B Hirshfeld Test Diff for    C21    --  C22     ..       7.57 su   
PLAT234_ALERT_4_B Large Hirshfeld Difference C33    --  C34A    ..       0.25 Ang. 
PLAT241_ALERT_2_B Check High      Ueq as Compared to Neighbors for        C27     
PLAT241_ALERT_2_B Check High      Ueq as Compared to Neighbors for        C33     

Alert level C
PLAT152_ALERT_1_C The Supplied and Calc. Volume s.u. Differ by ...          2 Units
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.78 Ratio
PLAT230_ALERT_2_C Hirshfeld Test Diff for    C33    --  C34B    ..       6.00 su   
PLAT234_ALERT_4_C Large Hirshfeld Difference C19    --  C24B    ..       0.17 Ang. 
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         C9     
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C17     
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C20     
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C21     
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C39     
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C19     
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C25     
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for        C31     
PLAT366_ALERT_2_C Short? C(sp?)-C(sp?) Bond  C31    -   C36    ...       1.36 Ang. 
PLAT910_ALERT_3_C Missing # of FCF Reflections Below Th(Min) .....          1      
PLAT911_ALERT_3_C Missing # FCF Refl Between THmin & STh/L=  0.600         43      
PLAT912_ALERT_4_C Missing # of FCF Reflections Above STh/L=  0.600         16      

Alert level G
PLAT003_ALERT_2_G Number of Uiso or Uij Restrained Atom Sites ....          4      
PLAT154_ALERT_1_G The su's on the Cell Angles are Equal  (x 10000)        300 Deg. 
PLAT242_ALERT_2_G Check Low       Ueq as Compared to Neighbors for       C34B     
PLAT301_ALERT_3_G Note: Main Residue  Disorder ...................          7 Perc.
PLAT773_ALERT_2_G Check long C-C Bond in CIF: C33    --  C34B    .       1.72 Ang. 
PLAT793_ALERT_4_G The Model has Chirality at P2      (Verify) ....          S      
PLAT793_ALERT_4_G The Model has Chirality at P3      (Verify) ....          R      
PLAT860_ALERT_3_G Note: Number of Least-Squares Restraints .......         24      

   0 ALERT level A = Most likely a serious problem - resolve or explain
   4 ALERT level B = A potentially serious problem, consider carefully
  16 ALERT level C = Check. Ensure it is not caused by an omission or oversight
   8 ALERT level G = General information/check it is not something unexpected

   2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  17 ALERT type 2 Indicator that the structure model may be wrong or deficient
   4 ALERT type 3 Indicator that the structure quality may be low
   5 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

Copyright © International Union of Crystallography
IUCr Webmaster