Acta Cryst. (2011). E67, m416-m417  [ doi:10.1107/S1600536811008075 ]

[1,2-Bis(diphenylphosphanyl)ethane-²P,P']{2-[(4-nitrobenzoylmethyl)diphenylphosphanyl]phenyl-²C,C'}palladium(II) trifluoromethanesulfonate-dichloromethane-n-hexane (1/1/0.5)

C. Rizzoli, K. Karami and F. Borzooie

Abstract: In the cation of the title compound, [Pd(C₂₆H₁₉NO₃P)(C₂₆H₂₄P₂)]CF₃O₃S·CH₂Cl₂·0.5C₆H₁₄, the Pd^II atom has a slightly tetrahedrally distorted square-planar coordination geometry. The PdC₃P and PdC₂P₂ five-membered metallacycles adopt envelope and twist conformations, respectively. In the crystal, intermolecular C-HO hydrogen bonds link cations and anions into a three-dimensional network. The dichloromethane solvent molecule is disordered over three orientations with a site-occupancy ratio of 0.5/0.3/0.2. The n-hexane solvent molecule has a crystallographically imposed centre of symmetry.

Online 9 March 2011

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