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Acta Cryst. (2011). E67, m394  [ doi:10.1107/S1600536811007227 ]

Bis(N,N,N-trimethylethanaminium) bis(1,4-tetraselenido-[kappa]2Se1,Se4)cadmate

J. Kim and K.-W. Kim

Abstract: The title compound, (EtMe3N)2[Cd(Se4)2], which has been prepared by reaction of CdI2, K2Se4 and EtMe3NI in dimethylformamide, is the first example of a [Cd(Se4)2]2- anion stabilized by alkylammonium counter-ions. The Cd atom in the complex [Cd(Se4)2]2- anion is tetrahedrally coordinated by two chelating tetraselenide ligands, and both CdSe4 rings exhibit an envelope conformation.

Online 2 March 2011


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