catena-Poly[[diaqua­bis­[2-(4-tolyl­sulfanyl)acetato-κO]manganese(II)]-μ-4,4′-bipyridine-κ2N:N′]

Zheng, X.-Y.

doi:10.1107/S1600536811011263

Volume 67
Part 5
Page m524
May 2011

Received 8 March 2011
Accepted 26 March 2011
Online 7 April 2011

Key indicators
Single-crystal X-ray study
T = 293 K
Mean (C-C) = 0.003 Å
R = 0.034
wR = 0.095
Data-to-parameter ratio = 16.7
Details

catena-Poly[[diaquabis[2-(4-tolylsulfanyl)acetato-O]manganese(II)]--4,4'-bipyridine-²N:N']

Xiao-Yong Zheng ^a ^*

^aWenzhou Medical College, Wenzhou, Zhejiang 325000, People's Republic of China
Correspondence e-mail: zhengxiaoyong71@yahoo.com.cn

In the polymeric title complex, [Mn(C₉H₉O₂S)₂(C₁₀H₈N₂)(H₂O)₂]_n, the Mn²⁺ cation and the 4,4'-bipyridine ligand lie on a twofold rotation axis. The cation has an MnN₂O₄ octahedral environment, being coordinated by the O atoms of two water molecules and two monodentate (4-tolylsulfanyl)acetate anions, and by two N atoms of two 4,4'-bipyridine ligands. The latter bridge adjacent cations into linear chains parallel to [010]. The chains are further linked with each other into a two-dimensional network parallel to (100) via intermolecular O-HO hydrogen bonds.

Related literature

For isotypic structures, see: Cai et al. (2008) for the Cd, Lin et al. (2006) for the Ni, and Zheng et al. (2006) for the Co analogue.

Experimental

Crystal data

[Mn(C₉H₉O₂S)₂(C₁₀H₈N₂)(H₂O)₂]
M_r = 609.60
Monoclinic, C 2/c
a = 21.750 (4) Å
b = 11.618 (2) Å
c = 11.028 (2) Å
= 93.24 (3)°
V = 2782.4 (10) Å³
Z = 4
Mo K radiation
= 0.67 mm^-1
T = 293 K
0.33 × 0.28 × 0.27 mm

Data collection

Bruker APEXII CCD diffractometer
Absorption correction: multi-scan (SADABS; Sheldrick, 1996) T_min = 0.800, T_max = 0.835
12205 measured reflections
3129 independent reflections
2806 reflections with I > 2(I)
R_int = 0.016

Refinement

R[F² > 2(F²)] = 0.034
wR(F²) = 0.095
S = 1.07
3129 reflections
187 parameters
3 restraints
H atoms treated by a mixture of independent and constrained refinement
_max = 0.67 e Å^-3
_min = -0.27 e Å^-3

Table 1
Selected bond lengths (Å)

Mn1-O1W	2.1843 (13)
Mn1-O2	2.1985 (12)
Mn1-N1	2.2593 (17)

Table 2
Hydrogen-bond geometry (Å, °)

D-HA	D-H	HA	DA	D-HA
O1W-H1WBO2ⁱ	0.83 (2)	2.00 (2)	2.7934 (16)	161 (2)
O1W-H1WAO1	0.83 (2)	1.87 (2)	2.6571 (19)	157 (2)
Symmetry code: (i) $[x, -y, z+{\script{1\over 2}}]$ .

Data collection: APEX2 (Bruker, 2006); cell refinement: SAINT (Bruker, 2006); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: DIAMOND (Brandenburg, 2006); software used to prepare material for publication: SHELXL97.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: WM2465 ).

Acknowledgements

The author thanks the Foundation of the Technology Department of Wenzhou City for financial support of this project (Y20090138).

References

Brandenburg, K. (2006). DIAMOND. Crystal Impact GbR, Bonn, Germany.
Bruker (2006). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Cai, W.-X., Zheng, X.-Y., Geng, X.-H. & Feng, Y.-L. (2008). Acta Cryst. E64, m1137.
Lin, H., Su, H. & Feng, Y. (2006). Acta Cryst. E62, m747-m749.
Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.
Zheng, X.-Y., Su, H. & Feng, Y.-L. (2006). Acta Cryst. E62, m1393-m1394.

metal-organic compounds

catena-Poly[[diaquabis[2-(4-tolylsulfanyl)acetato-O]manganese(II)]--4,4'-bipyridine-2N:N']