Acta Cryst. (2011). E67, o1156  [ doi:10.1107/S1600536811013699 ]

1-(9-Methyl-11-sulfanylidene-8-oxa-10,12-diazatricyclo[7.3.1.0^2,7]trideca-2,4,6-trien-13-yl)ethanone

M. M. Kurbanova, A. M. Maharramov, A. B. Novruzova, A. V. Gurbanov and S. W. Ng

Abstract: The six-membered oxacyclohexene ring of the title compound, C₁₃H₁₄N₂O₂S, is fused with the benzene ring and the quarternary C atom lies above the plane of the benzene ring by 0.229 (8) Å, whereas the methine C atom (which bears the acetyl substituent) lies below this plane by 0.595 (8) Å. The oxacyclohexene ring is also fused with the sofa-shaped 2,6-diazacyclohexanone ring. The methine C atom that belongs to both six-membered rings lies above the mean plane of the other five atoms (r.m.s. deviation = 0.077 Å) by 0.759 (5) Å. In the crystal, N-HS hydrogen bonds link adjacent molecules into a linear chain.

Online 16 April 2011

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