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Volume 67 
Part 6 
Page m663  
June 2011  

Received 20 April 2011
Accepted 26 April 2011
Online 7 May 2011

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Key indicators
Single-crystal X-ray study
T = 100 K
Mean [sigma](C-C) = 0.005 Å
R = 0.037
wR = 0.086
Data-to-parameter ratio = 18.6
Details
Open access

Chloridobis(2-chlorobenzyl)(quinolin-8-olato-[kappa]2N,O)tin(IV)

Thy Chun Keng,a Kong Mun Loa and Seik Weng Nga*

aDepartment of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia
Correspondence e-mail: seikweng@um.edu.my

The SnIV atom in the three independent molecules of the title compound, [Sn(C7H6Cl)2(C9H6NO)Cl], is N,O-chelated by the quinolin-8-olate anion and exists in a cis-C2SnNOCl trigonal-bipyramidal geometry; the O atom of the anion and the two benzyl C atoms lie in the equatorial plane.

Related literature

For the direct synthesis of the organotin chloride reactant, see: Sisido et al. (1961[Sisido, K., Takeda, Y. & Kinugawa, Z. (1961). J. Am. Chem. Soc. 83, 538-541.]). For related structures, see: Shi & Hu (1987[Shi, D.-S. & Hu, S.-Z. (1987). Chin. J. Struct. Chem. 6, 193-197.]); Vafaee et al. (2010[Vafaee, M., Amini, M. M. & Ng, S. W. (2010). Acta Cryst. E66, m964.]).

[Scheme 1]

Experimental

Crystal data

  • [Sn(C7H6Cl)2(C9H6NO)Cl]

  • Mr = 549.42

  • Monoclinic, P 21 /n

  • a = 10.2504 (1) Å

  • b = 41.2573 (6) Å

  • c = 15.3882 (2) Å

  • [beta] = 100.3433 (6)°

  • V = 6401.98 (14) Å3

  • Z = 12

  • Mo K[alpha] radiation

  • [mu] = 1.59 mm-1

  • T = 100 K

  • 0.25 × 0.20 × 0.15 mm
Data collection

  • Bruker SMART APEX diffractometer

  • Absorption correction: multi-scan (SADABS; Sheldrick, 1996[Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany.]) Tmin = 0.692, Tmax = 0.797

  • 41105 measured reflections

  • 14589 independent reflections

  • 13128 reflections with I > 2[sigma](I)

  • Rint = 0.024
Refinement

  • R[F2 > 2[sigma](F2)] = 0.037

  • wR(F2) = 0.086

  • S = 1.11

  • 14589 reflections

  • 784 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 1.27 e Å-3

  • [Delta][rho]min = -1.42 e Å-3

Data collection: APEX2 (Bruker, 2009[Bruker (2009). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT; data reduction: SAINT (Bruker, 2009[Bruker (2009). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: X-SEED (Barbour, 2001[Barbour, L. J. (2001). J. Supramol. Chem. 1, 189-191.]); software used to prepare material for publication: publCIF (Westrip, 2010[Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.]).

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: BT5528 ).

Acknowledgements

We thank the University of Malaya (grant No. RG020/09AFR) for supporting this study.

References

Barbour, L. J. (2001). J. Supramol. Chem. 1, 189-191.  [CrossRef] [ChemPort]
Bruker (2009). APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Shi, D.-S. & Hu, S.-Z. (1987). Chin. J. Struct. Chem. 6, 193-197.  [ChemPort]
Sisido, K., Takeda, Y. & Kinugawa, Z. (1961). J. Am. Chem. Soc. 83, 538-541.  [CrossRef] [ISI]
Vafaee, M., Amini, M. M. & Ng, S. W. (2010). Acta Cryst. E66, m964.  [CrossRef] [details]
Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.  [ISI] [CrossRef] [ChemPort] [details]

Acta Cryst (2011). E67, m663  [ doi:10.1107/S160053681101573X ]

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