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Volume 67 
Part 6 
Page o1478  
June 2011  

Received 3 May 2011
Accepted 16 May 2011
Online 20 May 2011

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Key indicators
Single-crystal X-ray study
T = 296 K
Mean [sigma](C-C) = 0.002 Å
R = 0.042
wR = 0.151
Data-to-parameter ratio = 21.9
Details
Open access

1,4-Bis[2-(prop-1-enyl)phenoxy]butane

Musa R. Bayramov,a Abel M. Maharramov,a Gunay M. Mehdiyeva,a* Shahnaz B. Hoseinzadeha and Rizvan K. Askerova

aBaku State University, Z. Khalilov St 23, Baku AZ-1148, Azerbaijan
Correspondence e-mail: mehdiyeva_gm@mail.ru

The molecule of the title compound, C22H26O2, exhibits Ci molecular symmetry with a crystallographic inversion centre at the mid-point of the central C-C bond. A kink in the molecule is defined by the torsion angle of 66.7 (2)° about this central bond of the alkyl bridge.

Related literature

For general background to the use of copolymerization reactions, see: Crivello et al. (1994[Crivello, J. V., Carter, A. M. & Bratslavsky, S. A. (1994). J. Polymer Sci. Part A Polymer Chem. 32, 2895-2909.]); Roshupkin & Kurmaz (2004[Roshupkin, V. P. & Kurmaz, S. V. (2004). Successes Chem. 73, 247-274.]); Askadsky (1998[Askadsky, A. A. (1998). Successes Chem. 67, 755-787.]).

[Scheme 1]

Experimental

Crystal data

  • C22H26O2

  • Mr = 322.43

  • Orthorhombic, P b c a

  • a = 5.4501 (10) Å

  • b = 15.825 (3) Å

  • c = 21.889 (4) Å

  • V = 1887.9 (6) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 0.07 mm-1

  • T = 296 K

  • 0.30 × 0.20 × 0.20 mm
Data collection

  • Bruker SMART APEXII CCD diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2001[Bruker (2001). SAINT-Plus and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.979, Tmax = 0.986

  • 20262 measured reflections

  • 2404 independent reflections

  • 1427 reflections with I > 2[sigma](I)

  • Rint = 0.040
Refinement

  • R[F2 > 2[sigma](F2)] = 0.042

  • wR(F2) = 0.151

  • S = 1.01

  • 2404 reflections

  • 110 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.15 e Å-3

  • [Delta][rho]min = -0.11 e Å-3

Data collection: APEX2 (Bruker, 2005[Bruker (2005). APEX2. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT-Plus (Bruker, 2001[Bruker (2001). SAINT-Plus and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: KP2326 ).

Acknowledgements

We thank Professor Victor N. Khrustalev for fruitful discussions and help in this work.

References

Askadsky, A. A. (1998). Successes Chem. 67, 755-787.
Bruker (2001). SAINT-Plus and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2005). APEX2. Bruker AXS Inc., Madison, Wisconsin, USA.
Crivello, J. V., Carter, A. M. & Bratslavsky, S. A. (1994). J. Polymer Sci. Part A Polymer Chem. 32, 2895-2909.  [ChemPort]
Roshupkin, V. P. & Kurmaz, S. V. (2004). Successes Chem. 73, 247-274.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]

Acta Cryst (2011). E67, o1478  [ doi:10.1107/S1600536811018538 ]

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