Acta Crystallographica Section E

Volume 67, Part 6 (June 2011)

organic compounds

wn2432 scheme

Acta Cryst. (2011). E67, o1355 [ doi:10.1107/S1600536811016874 ]

N-(Pyridin-2-ylmethyl)pyridin-2-amine

S.-H. Moon, T. H. Kim and K.-M. Park

Abstract: The title compound, C₁₁H₁₁N₃, crystallizes with two molecules (A and B) in the asymmetric unit. The geometries of both molecules are very similar, with the exception of the torsion angles of the inter-ring chains; the values for C-N-C-C are 67.4 (5) and -69.3 (5)° for molecules A and B, respectively. The dihedral angles between the pyridyl ring planes are 84.0 (2) and 83.2 (2)° for molecules A and B, respectively. In the crystal, weak intermolecular N-HN hydrogen bonds and C-H [pi] interactions contribute to the stabilization of the packing.


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