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Acta Cryst. (2011). E67, m717  [ doi:10.1107/S160053681101676X ]

Diaquabis(5-carboxy-2-ethyl-1H-imidazole-5-carboxylato-[kappa]2N3,O4)zinc trihydrate

G. Zhang

Abstract: In the crystal structure of the title compound, [Zn(C7H7N2O4)2(H2O)2]·3H2O, the ZnII ion, located an inversion center, is N,O-chelated by two 5-carboxy-2-ethyl-1H-imidazole-4-carboxylate anions and further coordinated by two water molecules in a distorted octahedral geometry. The carboxy group links with the carboxylate group of the same ligand via an intramolecular O-H...O hydrogen bond. An extensive intermolecular N-H...O and O-H...O hydrogen-bonded network exists in the crystal structure. One disordered lattice water molecule is half-occupied and is located close to an inversion center.

Online 7 May 2011


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