Acta Crystallographica Section E

Volume 67, Part 7 (July 2011)

metal-organic compounds

 

{Bis[2-(diphenylphosphanyl)ethyl]phenylphosphane-³P,P',P''}[(Z)-8-mesitylcyclooct-4-en-1-yl]platinum(II) tetrafluoridoborate dichloromethane disolvate

S.-B. Zhao, R.-Y. Wang and M. R. Gagné

Abstract: In the title ionic compound, [Pt(C₁₇H₂₃)(C₃₄H₃₃P₃)](BF₄)·2CH₂Cl₂, the Pt^II atom adopts a square-planar coordination geometry with the large (Z)-8-mesitylcyclooct-4-en-1-yl group occupying the fourth coordination site. The (triphos)Pt moiety and the mesityl group are attached to the cyclooct-4-ene motif at the 1- and 8-position in a syn configuration. The (BF₄)^- anion and one of the dichloromethane solvate molecules each are disordered over two sets of sites.

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	Chemdraw file (7.5 kbytes) [ doi:10.1107/S1600536811023853/jh2297Isup2.cdx ] Supplementary material

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