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Volume 67 
Part 7 
Page m998  
July 2011  

Received 2 June 2011
Accepted 21 June 2011
Online 30 June 2011

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Key indicators
Single-crystal X-ray study
T = 293 K
Mean [sigma](C-C) = 0.005 Å
R = 0.016
wR = 0.038
Data-to-parameter ratio = 15.7
Details
Open access

Poly[[diaqua-[mu]6-succinato-di-[mu]5-succinato-didysprosium(III)] monohydrate]

Wei Xu,a* Hai-Sheng Changa and Xia-Xia Guoa

aCenter of Applied Solid State Chemistry Research, Ningbo University, Ningbo, Zhejiang 315211, People's Republic of China
Correspondence e-mail: xuwei@nbu.edu.cn

The title compound, {[Dy2(C4H4O4)3(H2O)2]·H2O}n, is isostructural with other lanthanide succinates of the same formula. The DyIII atom is nine-coordinated in a tricapped trigonal-prismatic environment by eight O atoms, derived from six carboxylate groups and a water molecule. One of the independent succinate anions is located about a crystallographic inversion center and the uncoordinated water molecule lies on a twofold axis. The crystal structure comprises edge-shared DyO9 polyhedra linked by succinate bridges, forming a three-dimensional network architecture. Intra- and intermolecular O-H...O hydrogen bonds are present in the crystal structure.

Related literature

For related compounds, see: Perles et al. (2004[Perles, J., Iglesias, M., Ruiz-Valero, C. & Snejko, N. (2004). J. Mater. Chem. 14, 2683-2698.]); Serpaggi & Ferey (1999[Serpaggi, G. M. & Ferey, G. (1999). Micropor. Mesopor. Mat. 32, 311-318.]); He et al. (2007[He, Y.-K., Wang, X.-F., Zhang, L.-T., Han, Z.-B. & Ng, S. W. (2007). Acta Cryst. E63, m3019.]); Seguatni et al. (2004[Seguatni, A., Fakhfakh, M., Vauley, M. J. & Jouini, N. (2004). J. Solid State Chem. 177, 3402-3410.]); Zhou et al. (2005[Zhou, Y. F., Jiang, F. L., Yuan, D. Q., Wu, B. L. & Hong, M. C. (2005). J. Mol. Struct. 743, 21-27.]); Cui et al. (2005[Cui, G. H., Li, J. R. & Bu, X. H. (2005). J. Mol. Struct. 740, 187-191.]); Yu et al. (2006[Yu, B., Wang, X.-Q., Wang, R.-J., Shen, G.-Q. & Shen, D.-Z. (2006). Acta Cryst. E62, m1620-m1622.]); Li (2007[Li, F. (2007). Acta Cryst. E63, m840-m841.]).

[Scheme 1]

Experimental

Crystal data

  • [Dy2(C4H4O4)3(H2O)2]·H2O

  • Mr = 727.26

  • Monoclinic, C 2/c

  • a = 19.981 (4) Å

  • b = 7.7616 (16) Å

  • c = 13.868 (3) Å

  • [beta] = 121.49 (3)°

  • V = 1834.0 (9) Å3

  • Z = 4

  • Mo K[alpha] radiation

  • [mu] = 8.17 mm-1

  • T = 293 K

  • 0.45 × 0.20 × 0.14 mm
Data collection

  • Rigaku R-AXIS RAPID diffractometer

  • Absorption correction: multi-scan (ABSCOR; Higashi, 1995[Higashi, T. (1995). ABSCOR. Rigaku Corporation, Tokyo, Japan.]) Tmin = 0.154, Tmax = 0.319

  • 8691 measured reflections

  • 2093 independent reflections

  • 2016 reflections with I > 2[sigma](I)

  • Rint = 0.018
Refinement

  • R[F2 > 2[sigma](F2)] = 0.016

  • wR(F2) = 0.038

  • S = 1.09

  • 2093 reflections

  • 133 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 0.78 e Å-3

  • [Delta][rho]min = -0.73 e Å-3

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
O7-H7A...O3i 0.85 2.07 2.878 (3) 158
O7-H7B...O2ii 0.85 1.86 2.710 (3) 174
O8-H8W...O7 0.85 2.17 2.949 (4) 153
Symmetry codes: (i) [-x+{\script{1\over 2}}, -y+{\script{5\over 2}}, -z]; (ii) [-x+{\script{1\over 2}}, -y+{\script{3\over 2}}, -z].

Data collection: RAPID-AUTO (Rigaku, 1998[Rigaku (1998). RAPID-AUTO. Rigaku Corporation, Tokyo, Japan.]); cell refinement: RAPID-AUTO; data reduction: CrystalStructure (Rigaku/MSC, 2004[Rigaku/MSC (2004). CrystalStructure. Rigaku/MSC Inc., The Woodlands, Texas, USA.]); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: VM2100 ).

Acknowledgements

This project was supported by the Scientific Research Fund of Zhejiang Provincial Education Department (grant No. Y201017782). Thanks are also extended to the K. C. Wong Magna Fund of Ningbo University.

References

Cui, G. H., Li, J. R. & Bu, X. H. (2005). J. Mol. Struct. 740, 187-191.  [ISI] [CSD] [CrossRef] [ChemPort]
He, Y.-K., Wang, X.-F., Zhang, L.-T., Han, Z.-B. & Ng, S. W. (2007). Acta Cryst. E63, m3019.  [CSD] [CrossRef] [details]
Higashi, T. (1995). ABSCOR. Rigaku Corporation, Tokyo, Japan.
Li, F. (2007). Acta Cryst. E63, m840-m841.  [CSD] [CrossRef] [details]
Perles, J., Iglesias, M., Ruiz-Valero, C. & Snejko, N. (2004). J. Mater. Chem. 14, 2683-2698.  [ChemPort]
Rigaku (1998). RAPID-AUTO. Rigaku Corporation, Tokyo, Japan.
Rigaku/MSC (2004). CrystalStructure. Rigaku/MSC Inc., The Woodlands, Texas, USA.
Seguatni, A., Fakhfakh, M., Vauley, M. J. & Jouini, N. (2004). J. Solid State Chem. 177, 3402-3410.  [ISI] [CSD] [CrossRef] [ChemPort]
Serpaggi, G. M. & Ferey, G. (1999). Micropor. Mesopor. Mat. 32, 311-318.  [CrossRef] [ChemPort]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Yu, B., Wang, X.-Q., Wang, R.-J., Shen, G.-Q. & Shen, D.-Z. (2006). Acta Cryst. E62, m1620-m1622.  [CrossRef] [details]
Zhou, Y. F., Jiang, F. L., Yuan, D. Q., Wu, B. L. & Hong, M. C. (2005). J. Mol. Struct. 743, 21-27.  [ISI] [CSD] [CrossRef] [ChemPort]

Acta Cryst (2011). E67, m998  [ doi:10.1107/S1600536811024330 ]

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