Acta Crystallographica Section E

Volume 67, Part 7 (July 2011)

organic compounds

xu5240 scheme

Acta Cryst. (2011). E67, o1664 [ doi:10.1107/S1600536811021672 ]

Bis(tetramethylammonium) thiosulfate tetrahydrate

Y.-X. Yang and S. W. Ng

Abstract: The anion of the title salt, 2C₄H₁₂N⁺·S₂O₃^2-·4H₂O, possesses approximate C_3v symmetry. The water molecules themselves engage in hydrogen bonding, forming a ribbon running along the a axis; adjacent chains are linked to the thiosulfate anions by hydrogen bonds, forming a three-dimensional network. The cavities in the network are occupied by the tetramethylammonium counter ions.


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