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Volume 67 
Part 8 
Pages m1107-m1108  
August 2011  

Received 22 June 2011
Accepted 11 July 2011
Online 23 July 2011

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Key indicators
Single-crystal X-ray study
T = 293 K
Mean [sigma](C-C) = 0.008 Å
R = 0.035
wR = 0.081
Data-to-parameter ratio = 11.8
Details
Open access

Poly[aqua[[mu]5-5-(isonicotinamido)isophthalato][[mu]4-5-(isonicotinamido)isophthalato]cerium(III)silver(I)]

Xue Niea* and Jing-Nian Qua

aDepartment of Chemistry and Materials Science, Hengyang, Hunan 421008, People's Republic of China
Correspondence e-mail: xuehuanie@126.com

The 4d-4f heteronuclear title complex, [AgCe(C14H8N2O5)2(H2O)]n, has a three-dimensional framework structure, generated by the carboxylate and pyridyl groups of the 5-(isonicotinamido)isophthalate (INAIP) ligands bridging the metal ions. The CeIII atom is coordinated by eight O atoms from six INAIP ligands and a water molecule in a distorted tricapped trigonal-prismatic geometry, while the AgI atom has a distorted trigonal-planar AgN2O geometry. O-H...O and N-H...O hydrogen bonds and [pi]-[pi] interactions between the pyridine and benzene rings [centroid-centroid distances = 3.642 (4) and 3.624 (3) Å] stabilize the crystal structure.

Related literature

For background to coordination polymers, see: Abourahma et al. (2002[Abourahma, H., Moulton, B., Kravtsov, V. & Zaworotko, M. J. (2002). J. Am. Chem. Soc. 124, 9990-9991.]); Costes et al. (2004[Costes, J. P., Dahan, F., Donnadieu, B., Douton, M. J. R., Garcia, M. I. F., Bousseksou, A. & Tuchagues, J. P. (2004). Inorg. Chem. 43, 2736-2744.]); Kapoor et al. (2002[Kapoor, P., Pathak, A., Kapoor, R., Venugopalan, P., Corbella, M., Rodrmguez, M., Robles, J. & Llobet, A. (2002). Inorg. Chem. 41, 6153-6160.]). For background to lanthanide and transition metal heterometallic compounds, see: Chen et al. (2010[Chen, M.-S., Su, Z., Chen, M., Chen, S.-S., Li, Y.-Z. & Sun, W.-Y. (2010). CrystEngComm, 12, 3267-3276.]); Cheng et al. (2006[Cheng, J.-W., Zhang, J., Zheng, S.-T., Zhang, M.-B. & Yang, G.-Y. (2006). Angew. Chem. Int. Ed. 45, 73-77.]); Lin et al. (2009[Lin, X.-M., Ying, Y., Chen, L., Fang, H.-C., Zhou, Z.-Y., Zhan, Q.-G. & Cai, Y.-P. (2009). Inorg. Chem. Commun. 12, 316-320.]); Zhang et al. (2005[Zhang, M.-B., Zhang, J., Zheng, S.-T. & Yang, G.-Y. (2005). Angew. Chem. Int. Ed. 44, 1385-1388.]).

[Scheme 1]

Experimental

Crystal data

  • [AgCe(C14H8N2O5)2(H2O)]

  • Mr = 834.45

  • Triclinic, [P \overline 1]

  • a = 10.4869 (14) Å

  • b = 11.1540 (15) Å

  • c = 13.7276 (18) Å

  • [alpha] = 107.853 (1)°

  • [beta] = 106.778 (2)°

  • [gamma] = 102.885 (2)°

  • V = 1375.2 (3) Å3

  • Z = 2

  • Mo K[alpha] radiation

  • [mu] = 2.42 mm-1

  • T = 293 K

  • 0.20 × 0.14 × 0.10 mm
Data collection

  • Bruker APEX CCD diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 2001[Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.643, Tmax = 0.794

  • 6903 measured reflections

  • 4777 independent reflections

  • 4178 reflections with I > 2[sigma](I)

  • Rint = 0.053
Refinement

  • R[F2 > 2[sigma](F2)] = 0.035

  • wR(F2) = 0.081

  • S = 0.97

  • 4777 reflections

  • 406 parameters

  • H-atom parameters constrained

  • [Delta][rho]max = 1.40 e Å-3

  • [Delta][rho]min = -1.44 e Å-3

Table 1
Hydrogen-bond geometry (Å, °)

D-H...A D-H H...A D...A D-H...A
O1W-H1WA...O5i 0.85 2.08 2.836 (5) 147
O1W-H1WB...O4ii 0.85 2.01 2.691 (6) 137
N2-H2...O10iii 0.86 2.01 2.788 (7) 149
N4-H4...O4i 0.86 2.08 2.926 (6) 167
Symmetry codes: (i) -x+1, -y+1, -z+2; (ii) x+1, y, z; (iii) x, y+1, z.

Data collection: SMART (Bruker, 2007[Bruker (2007). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2007[Bruker (2007). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: HY2446 ).

Acknowledgements

This work was supported by the Hengyang Bureau of Science & Technology (grant No. 2009 K J28).

References

Abourahma, H., Moulton, B., Kravtsov, V. & Zaworotko, M. J. (2002). J. Am. Chem. Soc. 124, 9990-9991.  [ISI] [CSD] [CrossRef] [PubMed] [ChemPort]
Bruker (2001). SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2007). SMART and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA.
Chen, M.-S., Su, Z., Chen, M., Chen, S.-S., Li, Y.-Z. & Sun, W.-Y. (2010). CrystEngComm, 12, 3267-3276.  [CrossRef] [ChemPort]
Cheng, J.-W., Zhang, J., Zheng, S.-T., Zhang, M.-B. & Yang, G.-Y. (2006). Angew. Chem. Int. Ed. 45, 73-77.  [ISI] [CSD] [CrossRef] [ChemPort]
Costes, J. P., Dahan, F., Donnadieu, B., Douton, M. J. R., Garcia, M. I. F., Bousseksou, A. & Tuchagues, J. P. (2004). Inorg. Chem. 43, 2736-2744.  [CrossRef] [ChemPort]
Kapoor, P., Pathak, A., Kapoor, R., Venugopalan, P., Corbella, M., Rodrmguez, M., Robles, J. & Llobet, A. (2002). Inorg. Chem. 41, 6153-6160.  [CrossRef] [ChemPort]
Lin, X.-M., Ying, Y., Chen, L., Fang, H.-C., Zhou, Z.-Y., Zhan, Q.-G. & Cai, Y.-P. (2009). Inorg. Chem. Commun. 12, 316-320.  [CrossRef]
Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.  [CrossRef] [details]
Zhang, M.-B., Zhang, J., Zheng, S.-T. & Yang, G.-Y. (2005). Angew. Chem. Int. Ed. 44, 1385-1388.  [ISI] [CSD] [CrossRef] [ChemPort]

Acta Cryst (2011). E67, m1107-m1108   [ doi:10.1107/S1600536811027668 ]

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