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Acta Cryst. (2011). E67, m1044-m1045  [ doi:10.1107/S1600536811026493 ]

Aquachloridobis(2-{[3-(morpholin-4-yl)propyl]iminomethyl}phenolato)manganese(III) monohydrate

N. A. Ikmal Hisham, H. Khaledi and H. Mohd Ali

Abstract: In the title compound, [Mn(C14H19N2O2)2Cl(H2O)]·H2O, the MnIII atom is N,O-chelated by two monoanionic Schiff bases, forming two six-membered chelate rings. One Cl atom and one water molecule in trans positions complete a distorted octahedral geometry around the metal atom. In the crystal, the complex molecules and the uncoordinated water molecules are connected via O-H...N, O-H...O and O-H...Cl hydrogen bonds into layers parallel to the ac plane and these are consolidated by C-H...[pi] interactions. The layers are further linked into a three-dimensional network through C-H...O interactions.

Online 9 July 2011


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