Acta Cryst. (2011). E67, o1967-o1968 [ doi:10.1107/S1600536811026237 ]
Abstract: The title compound, C6H11N3O2S, consists of a roughly planar molecule (r.m.s deviation from planarity = 0.077 Å for the non-H atoms) and has the S atom in an anti position to the imine N atom. This N atom is the acceptor of a strongly bent internal N-HN hydrogen bond donated by the amino group. In the crystal, molecules are arranged in undulating layers parallel to (010). The molecules are linked via intermolecular amino-carboxyl N-HO hydrogen bonds, forming chains parallel to . The chains are cross-linked by Ncarbazone-HS and C-HS interactions, forming infinite sheets.
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