Acta Crystallographica Section E

Structure Reports Online

Volume 67, Part 10 (October 2011)

organic compounds

Acta Cryst. (2011). E67, o2690    [ doi:10.1107/S1600536811037731 ]

(Z)-Methyl 2-[(4-bromo-2-formyl­phen­oxy)meth­yl]-3-o-tolyl­acrylate

S. Vijayakumar, R. Madhanraj, S. Murugavel, R. Selvakumar and M. Bakthadoss

Abstract: In the title compound, C19H17BrO4, the dihedral angle between the two benzene rings is 82.1 (1)°. The mol­ecular structure is stabilized by an intra­molecular C-H...O hydrogen bond which generates an S(7) ring motif. The crystal packing is stabilized by inter­molecular C-H...O hydrogen bonds and C-H...[pi] inter­actions. Inter­molecular C-H...O inter­actions are involved in the formation of centrosymmetric R22(16) dimers, which are connected into supra­molecular tapes running along the [100] direction.

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