Acta Crystallographica Section E

Volume 67, Part 10 (October 2011)


organic compounds



bx2371 scheme

Acta Cryst. (2011). E67, o2629    [ doi:10.1107/S1600536811036403 ]

1-Heptyl-1,3,6,8-tetraazatricyclo[4.3.1.13,8]undecan-1-ium iodide

A. Rivera, J. Sadat-Bernal, J. Ríos-Motta, K. Fejfarová and M. Dusek

Abstract: The title compound C14H29N4+·I- salt, was obtained by the reaction of cage adamanzane-type aminal 1,3,6,8-tetraazatricyclo[4.3.1.13,8]undecane with heptyl iodide. In the cation, the bond lengths and angles are within normal ranges, except for one N-C(ring) bond distance of 1.542 (3) Å, which is unexpectedly long compared with related compounds. In the crystal, ions are linked through C-H...I hydrogen bonds. The crystal studied was a non-merohedral twin with a minor twin domain of 6.56 (5)%.


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