Acta Cryst. (2011). E67, m1337  [ doi:10.1107/S1600536811035811 ]

Dibromidooxido[(Z)-N'-(propan-2-ylidene)benzohydrazidato](triphenylphosphane)rhenium(V)

N. Yumata, T. Gerber and R. Betz

Abstract: The asymmetric unit of the title neutral rhenium(V) coordination compound, [ReBr₂(C₁₀H₁₁N₂O)O(C₁₈H₁₅P)], contains two molecules. In each of the two molecules the metal atom is octahedrally coordinated, the bromido ligands being cis-orientated. The chelate ligand is present in its imine-tautomeric form. In the crystal, C-HBr contacts connect the molecules into chains along [101]. The shortest intercentroid distance between two aromatic rings was found to be 3.906 (2) Å.

Online 14 September 2011

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