Acta Cryst. (2011). E67, m1337 [ doi:10.1107/S1600536811035811 ]
Abstract: The asymmetric unit of the title neutral rhenium(V) coordination compound, [ReBr2(C10H11N2O)O(C18H15P)], contains two molecules. In each of the two molecules the metal atom is octahedrally coordinated, the bromido ligands being cis-orientated. The chelate ligand is present in its imine-tautomeric form. In the crystal, C-HBr contacts connect the molecules into chains along . The shortest intercentroid distance between two aromatic rings was found to be 3.906 (2) Å.
Online 14 September 2011
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