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Acta Cryst. (2011). E67, o2562-o2563  [ doi:10.1107/S1600536811035495 ]

1,2-Bis(benzyloxy)-1,2-bis(4-chlorophenyl)-3,8-dimethoxyacenaphthene

T. Takada, D. Hijikata, A. Okamoto, H. Oike and N. Yonezawa

Abstract: In the title compound, C40H32Cl2O4, the two chlorobenzene rings are in syn orientations with respect to the naphthalene ring system and make dihedral angles of 57.12 (6) and 85.74 (6)° with it. The benzene rings of the benzyloxy group make dihedral angles of 75.34 (6) and 83.95 (7)°, with the naphthalene ring system. In the crystal, the molecules are linked by intermolecular C-H...Cl interactions between the methylene H atoms of the benzyloxy group and the Cl atoms in adjacent molecules. Furthermore, centrosymmetrically related molecules are linked into dimeric units by pairs of C-H...[pi] interactions.

Online 3 September 2011


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