Acta Cryst. (2011). E67, o2792  [ doi:10.1107/S1600536811039511 ]

N,N'-Bis(2-methylphenyl)-N''-(2,2,2-trichloroacetyl)phosphoric triamide

M. Pourayoubi, M. Keikha and M. Parvez

Abstract: In the title compound, C₁₆H₁₇Cl₃N₃O₂P, the P-N bonds in the P(O)[NH(2-CH₃)C₆H₄]₂ unit [1.623 (4) and 1.637 (3) Å] are shorter than the P-N bond in the C(O)NHP(O) fragment [1.704 (3) Å]. The phosphoryl and carbonyl groups are anti with respect to each other and the P atom has a distorted tetrahedral configuration. In the crystal, adjacent molecules are linked via N-HO(P) and N-HO(C) hydrogen bonds into an extended chain parallel to [101].

Online 30 September 2011

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