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Acta Cryst. (2011). E67, m1395  [ doi:10.1107/S160053681103697X ]

Tetrakis(diethyl ether)tetra-[mu]4-oxido-octakis(pentafluorophenyl)octazinc

D. Franz, H.-W. Lerner and M. Bolte

Abstract: Molecules of the title compound, [Zn8(C6F5)8O4(C4H10O)4], are located on a special position of site symmetry \\overline{4}. As a result, there is just one quarter-molecule in the asymmetric unit. The title compound features a Zn4O4 cube. Each Zn atom in the cube carries a pentafluorophenyl substituent. Each O atom is bonded to a further Zn atom, which is connected to a pentafluorophenyl substituent and the O atom of a diethyl ether molecule. All ether C atoms are disordered over two sets of sites with a site occupation factor of 0.51 (2) for the major occupied site.

Online 17 September 2011


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