Acta Cryst. (2011). E67, o2795 [ doi:10.1107/S160053681103950X ]
Abstract: In the anion of the title salt, C7H16N+·C21H35N3O3PS-, the P and S atoms are both in distorted tetrahedral environments and the angles at the tertiary N atoms confirm their sp2 character. The two S=O groups are in syn and gauche conformations with respect to the phosphoryl group. In the crystal, N-HO(=S) and N-HO(=P) hydrogen bonds involving two anions and two cations form a centrosymmetric four-component cluster.
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