Acta Crystallographica Section E

Volume 67, Part 10 (October 2011)


organic compounds



lh5320 scheme

Acta Cryst. (2011). E67, o2795    [ doi:10.1107/S160053681103950X ]

Cyclohexyl(methyl)ammonium {bis[cyclohexyl(methyl)amino]phosphoryl}(4-methylphenylsulfonyl)azanide

M. Pourayoubi, H. Fadaei, A. Tarahhomi and M. Parvez

Abstract: In the anion of the title salt, C7H16N+·C21H35N3O3PS-, the P and S atoms are both in distorted tetrahedral environments and the angles at the tertiary N atoms confirm their sp2 character. The two S=O groups are in syn and gauche conformations with respect to the phosphoryl group. In the crystal, N-H...O(=S) and N-H...O(=P) hydrogen bonds involving two anions and two cations form a centrosymmetric four-component cluster.


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